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Academic Journal of Engineering and Technology Science, 2018, 1(1); doi: 10.25236/AJETS.020004.

Synthesis and Structural Characterization of Bismuth(III) Complexes with Dithiocarbamate

Author(s)

Feng Li1, 2, Diansheng Liu1

Corresponding Author:
Feng Li
Affiliation(s)

1. Institute of Applied Chemistry, Shanxi University, Taiyuan, Shanxi 030006, P. R. China
2. Department of Chemistry and Chemical Engineering, Luliang University, Lishi Shanxi 033000 P.R. China

Abstract

Six new bismuth(III) complexes with dithiocarbamate {[NH (CH2CH2)2 NCS2]2BiI}2 (1), [(nBu2 NCS2)2 BiI]2 (2), {[O (CH2CH2)2 NCS2]2BiI}2 (3), {[ (CH2)5 NCS2]2 BiI}2 (4), {(Bz2NCS2)2BiI}2 (5), {(Et2NCS2)2BiI}2 (6) were synthesized by the reaction of bismuth triiodine and dithiocarbamate in 1:2 stoichiometry and characterized by elemental analysis, UV, IR and 1H NMR. The crystal structure of complex 1 was determined by X-ray single crystal diffraction. The structure shows that the bismuth atom is rendered six-coordinated in a distorted octahedron bipyramidal coordination geometries.

Keywords

Iodobismuth(III), Crystal structure, Dithiocarbamate

Cite This Paper

Feng Li, Diansheng Liu. Synthesis and Structural Characterization of Bismuth(III) Complexes with Dithiocarbamate. Academic Journal of Engineering and Technology Science (2018) Vol. 1: 34-44.

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