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Academic Journal of Materials & Chemistry, 2022, 3(2); doi: 10.25236/AJMC.2022.030202.

Development and Performance Study of Perovskite Graphene Photodetector

Author(s)

Xiaocan Chen1, Yuying Song2

Corresponding Author:
Xiaocan Chen
Affiliation(s)

1College of Physics and Optoelectronic Engineering, Shenzhen University, Shenzhen, 518060, China

2School of Physics, Changchun University of Science and Technology, Changchun, 130013, China

Abstract

Due to the lack of gain mechanism and poor light absorption ability of graphene, it is difficult for single-chip graphene photovoltaic devices to obtain high photovoltaic conversion efficiency. In view of this bottleneck, this paper aims to solve the above problems by preparing heterostructures with perovskite materials in graphene. The transfer process of graphene film was optimized to reduce the p-type doping of graphene field effect transistor and significantly improve its mobility. Polymethyl methacrylate technology is applied to the graphite process to solve the problem of channel carbonized photoresist residue in semiconductor devices. In addition, vertical graphene nanowalls (GNWs) were fabricated on Si substrates by radio frequency plasma enhanced chemical vapor deposition (RF plasma enhanced CVD), and then perovskite / GNWs hybrid photodetectors were obtained. The experimental results show that the device has high sensitivity and stable performance. In the wavelength range of 635 nm, the reaction speed of the element reaches 3.2 × 105 A / W, and the response time is 24 ms (descending edge) to 8 ms.

Keywords

perovskite, graphene, photodetector, field effect

Cite This Paper

Xiaocan Chen, Yuying Song. Development and Performance Study of Perovskite Graphene Photodetector. Academic Journal of Materials & Chemistry (2022) Vol. 3, Issue 2: 6-13. https://doi.org/10.25236/AJMC.2022.030202.

References

[1] Novoselov K S, Geim A K, Morozov S V, Jiang D, Katsnelson M I, Grigorieva I V, Dubonos S V, Firsov A A. Two-dimensional gas of massless Dirac fermions in graphene. [J]. Nature, 2005, 438(7065): 197-200.

[2] Feng Tingting. The preparation and characteristics of graphene field effect transistor [D]. Qinghua University, 2014: 18-22.

[3] Ge Bang Tong. Study on Graphene Matrix Composite Photodetectors [D]. Chongqing University, 2017: 1-5.

[4] Konstantatos G, Badioli M, Gaudreau L, et al. Hybrid graphene–quantum dot phototransistors with ultrahigh gain [J]. Nature Nanotechnology, 2012, 7(6): 363-368.

[5] Ran Qincui. Preparation and performance of graphene photodetectors [D]. Chongqing University of Technology, 2016: 11.

[6] Ramasamy P, Lim D H, Kim B, et al. All-inorganic cesium lead halide perovskite nanocrystals for photodetector applications [J]. Chemical Communications, 2015, 52(10): 2067-2070.

[7] Li Xingao, Wang Bolin, Liu Zhongru. Research progress in preparation, characterization and properties of graphene [J]. Materials Report, 2012, 26 (1): 61-65.

[8] Zhang Heng. Preparation and performance of graphene / perovskite photodetectors [D]. Harbin University of Technology, 2017: 20-21.

[9] Whelan Patrick R, Iwaszczuk Krzysztof, Wang Ruizhi, Hofmann Stephan, Bøggild Peter, Jepsen Peter Uhd. Robust mapping of electrical properties of graphene from terahertz time-domain spectroscopy with timing jitter correction. [J]. Optics express, 2017, 25(3): 2725-2733.

[10] Zhang L, Ni M, Liu D, et al. Competitive Growth and Etching of Epitaxial Graphene [J]. Journal of Physical Chemistry C, 2012, 116(51): 26929-26931.

[11] Preparation and performance study of Xu Xiang. Graphene-perovskite quantum dot composite photodetector [D]. Nanjing University of Posts and Telecommunications, 2020. DOI: 10.27251/d. cnki.gnjdc.2020.001567: 27-28.